Chemistry

Selenium boosts tellurium’s energy storage capacity in next-generation batteries

How the science connects

ElectrochemistryEnergy storageRedox reactions

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Researchers developed a novel battery chemistry using tellurium as the cathode material that achieves reversible six-electron transfer through selenium modulation, creating hypervalent tellurium species in aqueous sodium/zinc hybrid batteries. This approach overcomes the typical two-electron limitation of tellurium redox reactions by forming stable intermediate compounds that facilitate deeper electrochemical conversion. The selenium-doped tellurium cathode demonstrated high capacity, excellent cycling stability, and efficient energy storage performance in the aqueous electrolyte system.


This breakthrough could enable development of higher energy density aqueous batteries that are safer and more cost-effective than conventional lithium-ion systems. The multi-electron redox strategy may be applicable to other chalcogen-based electrode materials, potentially advancing grid-scale energy storage and sustainable battery technologies.


Source: Reversible six-electron tellurium redox enabled by selenium-modulated hypervalent activation in aqueous sodium/zinc hybrid batteries