Chemistry

Specially doped glass emits near-infrared light for advanced optical applications

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Rare earth elementEnergy transferLuminescence

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This study investigates barium gallo-germanate glasses doped with chromium (Cr3+) and erbium (Er3+) ions, with additional lanthanide ions (Yb3+ or Ho3+), designed to emit near-infrared light. The researchers demonstrate that Cr3+ acts as a sensitizer, absorbing visible light and transferring energy to Er3+ ions, which then produce enhanced near-infrared emission around 1.5 micrometers. The addition of Yb3+ or Ho3+ further modifies the energy transfer pathways and luminescence properties of the glass systems.


These specialized glasses have potential applications in optical amplifiers for telecommunications, near-infrared light sources, and photonic devices. The ability to tune near-infrared emission through strategic ion doping could improve fiber-optic communication systems and enable new sensing technologies operating in the infrared spectrum.


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Source: Barium gallo-germanate glasses co-activated with Cr3+/Er3+ and Cr3+/Er3+/Ln3+ (Ln = Yb, Ho) for near-infrared luminescence applications