Chemistry

[ASAP] Polymer-Modulated Solvation Chemistry via Compatibilizing-Solvent Plasticization for Stable High-Energy Lithium Metal Batteries

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This study introduces a polymer-modulated solvation chemistry approach in which a compatibilizing solvent acts as a plasticizer to tune the electrolyte structure in lithium metal batteries. By incorporating a tailored polymer into the electrolyte system, the researchers alter the solvation shell of lithium ions, promoting the formation of a more stable solid electrolyte interphase on the lithium metal anode. The modified electrolyte demonstrates improved cycling stability and enhanced energy density compared to conventional electrolyte formulations.


Lithium metal batteries are considered a next-generation energy storage technology due to their high theoretical capacity, and addressing their instability through electrolyte engineering could accelerate the development of safer, longer-lasting batteries for electric vehicles and portable electronics.


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Journal of the American Chemical Society
DOI: 10.1021/jacs.6c02800

Source: [ASAP] Polymer-Modulated Solvation Chemistry via Compatibilizing-Solvent Plasticization for Stable High-Energy Lithium Metal Batteries