Physics

Fast and slow surfactants in turbulence-driven bubble breakup

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TurbulenceSurfactant

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This study examines how surfactants and salt affect the breakup of large air cavities in turbulent water flows. Researchers found that certain surfactants can increase bubble production by up to five times, but only when they adsorb to bubble surfaces quickly enough to keep pace with the rapid formation of new interfaces during turbulent breakup. The effect is most pronounced for bubbles smaller than the Hinze scale, where surface tension and turbulence forces balance, while larger bubbles show unchanged size distributions regardless of surfactant presence.


Understanding surfactant effects on bubble formation in turbulent flows has practical applications in industrial processes like chemical reactors, wastewater treatment, and flotation separation where controlling bubble size distributions is critical for efficiency. The findings could help optimize these processes by selecting surfactants with appropriate adsorption rates.


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Abstract: When a large air cavity breaks in a turbulent flow, it goes through very large deformations and cascading events of new interface formation, including elongated filaments and bubbles over a wide range of scales, with their rate of formation controlled by turbulence and capillary processes. We experimentally investigate the effects of surfactants and salt on the fragmentation, and observe a five fold increase of the number of bubbles being produced in some cases. For bubbles larger than the Hinze scale $d_H$ (defined as the balance between surface tension and turbulence stresses), we observe that bubble size distributions remain unchanged for all solutions tested. For bubbles below $d_H$, however, we observe an increase of the number of bubbles produced and an associated steepening of the bubble size distribution upon the addition of surfactant or salt. This later effect is only visible for some of the surfactants tested when their adsorption timescale is fast enough compared to the rate at which new interfaces are being generated by turbulence.

Source: Fast and slow surfactants in turbulence-driven bubble breakup