Chemistry

Supramolecular morphological transition driven by nonequilibrium break-and-build self-organisation

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Supramolecular che…Self-assemblyNon-equilibrium th…

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This study demonstrates a chemical system that undergoes morphological transitions in supramolecular structures through a "break-and-build" mechanism driven by nonequilibrium conditions. The researchers show that by continuously supplying chemical fuel, they can control the assembly and disassembly of molecular structures, causing them to switch between different shapes and organizations. This process mimics biological systems where energy input drives dynamic structural changes, allowing materials to exist in states that would be impossible under equilibrium conditions.


This work advances our understanding of how to create synthetic materials that behave like living systems, with potential applications in adaptive materials, drug delivery systems, and soft robotics. The ability to control material properties through fuel-driven cycles could enable development of self-healing materials and responsive devices that adapt to environmental changes.


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Source: Supramolecular morphological transition driven by nonequilibrium break-and-build self-organisation