Chemistry

[ASAP] Asymmetric Glycol-Ether Molecule Design Enables Temperature-Adaptive Anion Coordination for Durable High-Temperature Sodium Batteries

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This study presents the design of an asymmetric glycol-ether molecule intended to achieve temperature-adaptive anion coordination in electrolytes for sodium-ion batteries operating at high temperatures. The molecular architecture is engineered so that its solvation behavior adjusts dynamically with temperature, optimizing ion transport and interfacial stability under demanding thermal conditions. The approach demonstrates improved cycling durability and electrochemical performance in high-temperature sodium battery systems compared to conventional electrolyte designs.


Sodium-ion batteries are considered a cost-effective alternative to lithium-ion systems for grid-scale energy storage, and improving their thermal stability is critical for deployment in environments subject to elevated temperatures. This work provides a molecular-level design strategy that could inform the development of more robust electrolytes for practical sodium battery applications.


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Journal of the American Chemical Society
DOI: 10.1021/jacs.6c01657

Source: [ASAP] Asymmetric Glycol-Ether Molecule Design Enables Temperature-Adaptive Anion Coordination for Durable High-Temperature Sodium Batteries