Physics

Insights into the Nature of Quantum Emitters in Electron-Irradiated hexagonal Boron Nitride

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This study investigates the origin of green-yellow quantum emitters in electron-irradiated hexagonal boron nitride (hBN), a material under active development for quantum technology applications. Using hyperspectral imaging, thermal annealing, and oxygen plasma etching, the researchers systematically ruled out organic contamination as the source of the observed emission lines, confirming the emitters are intrinsic to the hBN material. The work further characterizes the spectral variability, thermal stability, and spatial localization of these emitters, and demonstrates that stable single-photon emitters can be created in hBN films thinner than 10 nm without any pre- or post-processing steps.


Reliably identifying and controlling quantum emitters in hBN is a prerequisite for their integration into quantum photonic devices such as single-photon sources, which are key components in quantum communication and computing systems. This framework offers practical guidance for distinguishing genuine intrinsic defects from contamination artifacts, which could improve reproducibility across laboratories working on hBN-based quantum technologies.


arXiv:2605.12663v1 Announce Type: new
Abstract: Quantum emitters in hexagonal boron nitride (hBN) have emerged as a promising solid-state platform for quantum technology applications. However, a persistent challenge in the field is the unclear origin of many observed emission lines, particularly in the visible range, which can be difficult to distinguish from signals arising from organic or process-induced contamination during sample preparations and handling. This ambiguity limits both the reproducibility of emitter generation and the reliable identification of truly intrinsic quantum defects. This work provides a step-by-step framework to assess whether quantum emitters in electron-irradiated hBN are associated with organic contaminants introduced during sample preparation. We employ hyperspectral imaging, thermal annealing, and oxygen plasma etching to investigate the origin of the green-yellow emitters in electron-irradiated hBN. The combined results not only rule out organic contamination as the source of emission but also provide insight into the spectral variability, thermal stability, and vertical localization of the emitters generated in electron-irradiated hBN that was created without any pre- or post-processing. In addition, our experiments demonstrate the feasibility of creating stable emitters in hBN with thicknesses below 10 nm. These findings provide practical guidance for the identification and controlled implementation of hBN-based single-photon emitters in quantum photonic devices.

Source: Insights into the Nature of Quantum Emitters in Electron-Irradiated hexagonal Boron Nitride